Chemical bonding - Born-Haber Cycle, Ionic Bonds, Covalent Bonds | Britannica

chemical bonding

Table of Contents

Introduction
Historical review
- Emergence of quantitative chemistry
  - The law of conservation of mass
  - The law of definite proportions
  - The law of multiple proportions
  - Dalton’s atomic theory
- Features of bonding
  - Valence
  - Ionic and covalent compounds
- The periodic table
- Additional evidence of atoms
  - Avogadro’s law
  - Kinetic theory of gases
  - Visual images of atoms
- Molecular structure
- Internal structure of atoms
  - Discovery of the electron
  - Contributions of Lewis
Atomic structure and bonding
- Atomic structure
  - The Bohr model
  - The quantum mechanical model
    - The location of the electron
    - Quantum numbers
  - Shapes of atomic orbitals
  - The building-up principle
    - Hydrogen and helium
    - Lithium through neon
    - Sodium through argon
    - Potassium through krypton
- Periodic arrangement and trends
  - Arrangement of the elements
  - Periodic trends in properties
    - Atomic size
    - Ionization energy
    - Electron affinity
    - Electronegativity
Bonds between atoms
- The formation of ionic bonds
  - Lewis formulation of an ionic bond
  - The Born-Haber cycle
  - Factors favouring ionic bonding
- Covalent bonds
  - Lewis formulation of a covalent bond
  - Advanced aspects of Lewis structures
    - Multiple bonds
    - Resonance
    - Hypervalence
    - Incomplete-octet compounds
    - Electron-deficient compounds
- Molecular shapes and VSEPR theory
  - Applying VSEPR theory to simple molecules
  - Molecules with multiple bonds
  - Molecules with no central atom
  - Limitations of the VSEPR model
- The polarity of molecules
The quantum mechanics of bonding
- Valence bond theory
  - Formation of σ and π bonds
  - Promotion of electrons
  - Hybridization
  - Resonant structures
- Molecular orbital theory
  - Molecular orbitals of H₂ and He₂
  - Molecular orbitals of period-2 diatomic molecules
  - Molecular orbitals of polyatomic species
  - The role of delocalization
  - Comparison of the VB and MO theories
Intermolecular forces
- Repulsive force
- Dipole–dipole interaction
- Dipole–induced-dipole interaction
- Dispersion interaction
- The hydrogen bond
Varieties of solids
- Ionic solids
- Molecular solids
- Network solids
- Metals
Advanced aspects of chemical bonding
- Theories of bonding in complexes
  - Crystal field theory
  - Ligand field theory
- Compounds displaying unique bonding
  - Organometallic compounds
  - Boranes
  - Metal cluster compounds
- Computational approaches to molecular structure

References & Edit History Related Topics

Images & Videos

crystal bonding

molecular structure

Witness a combustion reaction between oxygen and cellulose to produce water, carbon dioxide, and carbon

See how John Dalton built his atomic theory on principles laid out by Henry Cavendish and Joseph-Louis Proust

Investigate the magnetlike ionic bond formed when electrons transfer from one atom to another

Rutherford atomic model

Bohr atomic model of a nitrogen atom

For Students

bonding summary

Read Next

molecule model, element

Molecular Machines: Making for the Future

Discover

Queen Elizabeth II addresses at opening of Parliament. (Date unknown on photo, but may be 1958, the first time the opening of Parliament was filmed.)

All 119 References in “We Didn’t Start the Fire,” Explained

Mona Lisa, oil on wood panel by Leonardo da Vinci, c. 1503-06; in the Louvre, Paris, France. 77 x 53 cm.

Why Is the Mona Lisa So Famous?

Pluto. The Changing Faces of Pluto. Most detailed view to date of the entire surface of the dwarf planet Pluto, as constructed from multiple NASA Hubble Space Telescope photographs taken from 2002 to 2003.

10 Important Dates in Pluto History

Aphrodite. Greek mythology. Sculpture. Aphrodite is the Greek goddess of love and beauty.

12 Greek Gods and Goddesses

VAN, TURKEY - OCTOBER 25: A building and car ruined during the earthquake of Van-Ercis on October 25, 2011 in Van, Turkey. It is 604 killed and 4152 injured in Van-Ercis Earthquake.

What Is an Aftershock?

earthquake. Heavily damaged school in the town of Yingxiu after a major earthquake struck China's Sichuan Province on May 12, 2008.

The 6 Deadliest Earthquakes Since 1950

Adolf Hitler (Nazi, nazism, German leader).

9 Things You Might Not Know About Adolf Hitler

The analysis of the formation of an ionic compound from its elements is commonly discussed in terms of a Born-Haber cycle, which breaks the overall process into a series of steps of known energy. The Born-Haber cycle for the formation of sodium chloride is shown in Figure 5. At the start of the cycle, the elements are considered to be in the form in which they exist at normal pressure and temperature. First, sodium metal is vaporized to a gas of sodium atoms. This step requires an input of energy known as the atomization energy of sodium metal. Next, the ...(100 of 27318 words)

Access the full article

Help support true facts by becoming a member.