Ferromagnetism

Role of exchange interaction

The magnetic properties of iron are thought to be the result of the magnetic moment associated with the spin of an electron in an outer atomic shell—specifically, the third d shell. Such electrons are referred to as magnetization electrons. The Pauli exclusion principle prohibits two electrons from having identical properties; for example, no two electrons can be in the same location and have spins in the same direction. This exclusion can be viewed as a “repulsive” mechanism for spins in the same direction; its effect is opposite that required to align the electrons responsible for the magnetization in the iron domains. However, other electrons with spins in the opposite direction, primarily in the fourth s atomic shell, interact at close range with the magnetization electrons, and this interaction is attractive. Because of the attractive effect of their opposite spins, these s-shell electrons influence the magnetization electrons of a number of the iron atoms and align them with each other.

A simple empirical representation of the effect of such exchange forces invokes the idea of an effective internal, or molecular, field H_int, which is proportional in size to the magnetization M; that is, H_int = λM in which λ is an empirical parameter. The resulting magnetization M equals χ_p(H + λM), in which χ_p is the susceptibility that the substance would have in the absence of the internal field. Assuming that χ_p = C/T, corresponding to Curie’s law, the equation M = C(H + λM)/T has the solution χ = M/H = C/(T − Cλ) = C/(T − Tc). This result, the Curie–Weiss law, is valid at temperatures greater than the Curie temperature T_c (see below); at such temperatures the substance is still paramagnetic because the magnetization is zero when the field is zero. The internal field, however, makes the susceptibility larger than that given by the Curie law. A plot of 1/χ against T still gives a straight line, as shown in Figure 16, but 1/χ becomes zero when the temperature reaches the Curie temperature.

Since 1/χ = H/M, M at this temperature must be finite even when the magnetic field is zero. Thus, below the Curie temperature, the substance exhibits a spontaneous magnetization M in the absence of an external field, the essential property of a ferromagnet. The Table gives Curie temperature values for various ferromagnetic substances.

In the ferromagnetic phase below the Curie temperature, the spontaneous alignment is still resisted by random thermal energy, and the spontaneous magnetization M is a function of temperature. The magnitude of M can be found from the paramagnetic equation for the reduced magnetization M/M_s = f(mB/kT) by replacing B with μ(H + λM). This gives an equation that can be solved numerically if the function f is known. When H equals zero, the curve of (M/M_s) should be a unique function of the ratio (T/T_c) for all substances that have the same function f. Such a curve is shown in Figure 17, together with experimental results for nickel and a nickel–copper alloy.

The molecular field theory explains the existence of a ferromagnetic phase and the presence of spontaneous magnetization below the Curie temperature. The dependence of the magnetization on the external field is, however, more complex than the Curie–Weiss theory predicts. The magnetization curve is shown in Figure 18 for iron, with the field B in the iron plotted against the external field H. The variation is nonlinear, and B reaches its saturation value S in small fields. The relative permeability B/μ₀H attains values of 10³ to 10⁴ in contrast to an ordinary paramagnet, for which μ is about 1.001 at room temperature. On reducing the external field H, the field B does not return along the magnetization curve. Even at H = 0, its value is not far below the saturation value.

Remanence

When H = 0 (labeled R in Figure 18), the magnetic field constitutes what is termed the residual flux density, and the retention of magnetization in zero field is called remanence. When the external field is reversed, the value of B falls and passes through zero (point C) at a field strength known as the coercive force. Further increase in the reverse field H sets up a reverse field B that again quickly reaches a saturation value S′. Finally, as the reverse field is removed and a positive field applied, B traces out the lower broken line back to a positive saturation value. Further cycles of H retrace the broken curve, which is known as the hysteresis curve, because the change in B always lags behind the change in H. The hysteresis curve is not unique unless saturation is attained in each direction; interruption and reversal of the cycle at an intermediate field strength results in a hysteresis curve of smaller size.

To explain ferromagnetic phenomena, Weiss suggested that a ferromagnetic substance contains many small regions (called domains), in each of which the substance is magnetized locally to saturations in some direction. In the unmagnetized state, such directions are distributed at random or in such a way that the net magnetization of the whole sample is zero. Application of an external field changes the direction of magnetization of part or all of the domains, setting up a net magnetization parallel to the field. In a paramagnetic substance, atomic dipoles are oriented on a microscopic scale. In contrast, the magnetization of a ferromagnetic substance involves the reorientation of the magnetization of the domains on a macroscopic scale; large changes occur in the net magnetization even when very small fields are applied. Such macroscopic changes are not immediately reversed when the size of the field is reduced or when its direction is changed. This accounts for the presence of hysteresis and for the finite remanent magnetization.

The technological applications of ferromagnetic substances are extensive, and the size and shape of the hysteresis curve are of great importance. A good permanent magnet must have a large spontaneous magnetization in zero field (i.e., a high retentivity) and a high coercive force to prevent its being easily demagnetized by an external field. Both of these imply a “fat,” almost rectangular hysteresis loop, typical of a hard magnetic material. On the other hand, ferromagnetic substances subjected to alternating fields, as in a transformer, must have a “thin” hysteresis loop because of an energy loss per cycle that is determined by the area enclosed by the hysteresis loop. Such substances are easily magnetized and demagnetized and are known as soft magnetic materials.